Zeolite-supported metal oxide sorbents for hot-gas desulfurization pdf
Keywords: zinc titanate sorbents, Hot-Gas Desulfurization (HGD), graphite The gas desulphurisation at high temperatures (HTGD) is one of the main process for retention of H
Zeolite-supported metal oxide sorbents for hot-gas desulfurization Galvin, L.D.G.; Atımtay, A.T.; Gupta, R.P. Impact of aqueous impregnation on the long-range ordering and mesoporous structure of cobalt containing MCM-41 and SBA-15 materials
A.3 Atımtay, A.T., Cleaner Energy Production with Integrated Gasification Combined Cycle Systems and Use of Metal Oxide Sorbents for Coal Gas Cleanup. “Clean Products and Processes” , …
A general overview of the supported sorbents for the removal of H2S from coal gas at high temperatures is given. As support material γ-Alumina, zirconia, zeolites, etc. can be used.
The experimental section describes the preparation and characterization methods used in this work for synthesizing sorbents. which gives an overview about the need of new technologies for coal utilization and importance of hot gas clean up. and composition of the mixed metal oxide sorbent and mixed metal oxide supported-ion exchanged zeolite (MMS-IZ) sorbents This thesis is comprised of
Abstract. Extrudates of regenerable mixed-metal oxide sorbents including zinc ferrite, copper-modified zinc ferrite, and zinc titanate were prepared and tested for their potential to remove hydrogen sulfide (H 2 S) from coal gasifier gas in a high-temperature high-pressure (HTHP) fixed-bed reactor.
Desulfurization of fuel gas can be achieved by using metal oxide sorbents that form stable sulfides. Elseviers and Verelst (1999) analysed the purification performance of different metal oxides between 350 K and 923 K, and ranked Cu, Zn, Co and Mo as being the most useful.
Review of H2S Sorbents at Low-Temperature Desulfurization of Biogas – Free download as PDF File (.pdf), Text File (.txt) or read online for free.
Yang, H., 2007, “Gas Phase Desulfurization Using Regenerable Microfibrous Entrapped Metal Oxide Based Sorbent for Logistic PEM Fuel Cell Applications,” Ph.D. …
This paper discusses the results obtained in an ongoing study geared towards developing advanced mixed-metal oxide sorbents for desulfurization of coal-derived fuel gases in the temperature range of 350 to 550°C. The paper focuses on the study related to the development of durable sorbents suitable for fluidized-bed application and addresses thermodynamic considerations, sulfidation kinetics
1: Gasper-Galvin L D, Atimtay A T, Gupta R P. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Industrial & Engineering Chemistry Research, 1998, 37(10): 4157-4166
Core-in-shell sorbent for hot coal gas desulfurization Abstract A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired
Abstract. Natural gas, refinery gas, and coal gas contain acid gases such as hydrogen sulfide (H 2 S) and carbon dioxide that must be removed from the gas stream due to the toxicity of H 2 S and to prevent corrosion to piping and production facility caused by the acid gases.
Hot Gas Desulfurization (HGD) technology, which is predicted for use in Clean Coal Technologies (IGCC, PFBC & MCFC), is a technique for removing sulfur compounds (H2S, COS) from fuel gas or coal gas by using regenerable metal oxide sorbents at a high temperature (350-650oC) and high pressure (20-30 bar) [Song et al., 2000]. HGD technology is a key element in the optimal devel-opment of the
“Regeneration of Sulfided Sorbents and Direct Production of Elemental Sulfur,” presented at the NATO/ASI Symposium on Desulfurization of Hot Coal Gas With Regenerable Metal Oxide Sorbents, Kuşadası, Turkey, July 1996, proceedings to be published.
The Author(s) 2016 removal for solid oxide fuel Reprints
Semi-Coke–Supported Mixed Metal Oxides for Hydrogen
Efficient, regenerable sorbents for removal of H 2 S from moderately high temperature (usually 200° C.-550°C.) gas streams comprise a porous, high surface area aluminosilicate support, suitably a zeolite, and most preferably a sodium deficient zeolite containing 1 to 20 weight percent of binary metal oxides. The binary oxides are a mixture of
High-Temperature H2S Removal from Fuel Gases by Regenerable Zinc Oxide-Titanium Dioxide Sorbents Early work on hot gas desulfurization employed single oxide sorbents, especially iron oxide and zinc oxide *To whom all correspondence should be addressed. Present address: Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA 70803. (MERC, 1978; …
Abstract. Desulfurization of natural gas is achieved commercially by absorption with liquid amine solutions. Adsorption technology could potentially replace the solvent extraction process, particularly for the emerging shale gas wells with production rates that are generally lower than that from the large conventional reservoirs, if a superior
Investigation of CuO/mesoporous SBA-15 sorbents for hot gas desulfurization Investigation of CuO/mesoporous SBA-15 sorbents for hot gas desulfurization Karvan, Oğuz; Atakül, Hüsnü 2008-09-01 00:00:00 Metal oxides, are widely used as sorbents to remove H 2 S from hot gases produced by gasification processes.
Abstract −The desulfurization abilities using GC/microreactor have been examined for CuO-Fe2O3 sorbents with respect to calcination temperatures of 700, 900 and 1,100 o C. CuO was used as a main active component, Fe
A fly ash sample was used as sorbent for trace element (As, Se, Cd and Zn) species at high temperatures in flue gases from coal gasification. The influence of temperature (550 and 750 °C) and gas composition (with and without H 2 S and HCl) on retention capacity was evaluated.
number of metal oxides from being used as a high temperature desulfurization sorbent. Westmoreland and Harrison(2) in their 1976 paper screened 28 solids with respect to their high temperature desulfurization potentials.
Copper-cobalt, copper-cerium mixed metal oxide and mixed metal oxide supported- ions exchanged on natural zeolite (MMS-IZ) sorbents are studied in this work. Copper-cobalt mixed system is a good candidate for low temperature desulfurization while copper-cerium exhibits the high temperature stability and high performance. The reduced form of cerium oxide (CeOn) in copper-cerium reduced the H2S
The Mn x Mo y /KIT-1 sorbents with different Mn/Mo molar ratio were prepared by a sol–gel method. The structural properties of these sorbents were investigated by XRD, N 2-adsorption, H 2-TPR, TEM, SEM, XPS and TG/DSC techniques.
Cüneyt Karakaya, Yurdanur Türker, Cemal Albayrak and Ömer Dag, Assembly of Molten Transition Metal Salt–Surfactant in a Confined Space for the Synthesis of Mesoporous Metal Oxide-Rich Metal Oxide–Silica Thin Films, Chemistry of Materials, 23, 12, (3062), (2011).
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin* Federal Energy Technology Center, U.S. Department of Energy, 3610 Collins Ferry Road,…
13/07/1993 · A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200° to about 1600° F.
12/10/1993 · The mixed metal oxide sorbent of the invention supported on zeolite (preferably copper and molybdenum on 4A Zeolite) has been found to remove hydrogen sulfide from a hydrogen-steam rich gas mixture at 256°-538° C. and regenerated to full capacity …
copper-cerium mixed metal oxide sorbents for hot gas desulfurization capable of withstanding the wide temperature range of application and multiple sulfidation-regeneration cycles. The regeneration path was reported as (Li et al. 1997).ion exchanged zeolites as the potential sorbents for desulfurization over a wide temperature range. An effort is made in this work to include the various
oxide and a zeolite adsorbent. H Desulfurization of fuel gas can be achieved by using metal oxide sorbents that form stable sulfides. Elseviers and Verelst (1999) analysed the purification performance of different metal oxides between 350K and 923K, and ranked Cu, Zn, Co and Mo as being the most useful. ZnO has been widely used to remove H 2S at moderate low temperatures because of its
98/02032 Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide : Poston, J. A. U.S. US 5,693,588 (Cl. 502
Abstract Removal of COS is more difficult than that of H2S from coal gas. It has been found that the reactions of H2S to COS may take place in sulfidation tests of sorbent at high temperatures. The formation of COS at high temperatures in simulated coal gas without sorbent and removal of COS with sorbent was mainly discussed in this article. A
Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures.
A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree.
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin * Federal Energy Technology Center, U.S. Department of Energy, …
Abstract. Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures.
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Get this from a library! Test and characterization of some zeolite supported gas phase desulfurization sorbents.. [Charles Rong; Deryn Chu; John Hopkins; U.S. Army Research Laboratory.] — This report presents the results of sulfidation and regeneration of mixed metal oxide supported on zeolite-Y for hydrogen sulfide (H2S) at 650 and 800 deg C
Similarly, advances made in sorbent technology, especially metal oxide sorbents, have resulted in effective sulfur emissions mitigation. Current use of metal oxide sorbents, however, has focused on, regenerable formulations which have excellent sulfur affinity but high physical attrition, resulting in poor overall economics.
A Mn-based sorbent with high desulfurization efficiency were fabricated using various mesoporous silica as support and doping rare earth oxides, and their physical properties were characterized by means of XRD, BET, H 2-TPR, CO 2-TPD, O 2-TPD and UV–Vis techniques.
A number of mixed metal oxide sorbents were tried, to achieve better performance in H 2 S removal, including ZnFe 2 O 4 (Ahmed et al., 2000) and Zn 2 TiO 4 (Lew and Sarofim, 1992a). Lew and Sarofim reported that Zn–Ti–O sorbent exhibited a high activity for hydrogen sulfide removal via a mechanism of desulfurization similar with that on ZnO. However, there are still some disadvantages for
The fluidized bed copper oxide process is an advanced technology for controlling SO2 and NOx emissions from coal-fired power plants. The development of this process has been sponsored by the U.S. Department of Energy’s Pittsburgh Energy Technology Center (DOE/PETC). Testing of the copper oxide process began at PETC in 1975 and has progressed through several stages in three different …
Bench-scale testing of high-temperature desulfurization
Abstract. Efficient, regenerable sorbents for removal of H.sub.2 S from moderately high temperature (usually 200.degree. C.-550.degree.C.) gas streams comprise a porous, high surface area aluminosilicate support, suitably a zeolite, and most preferably a sodium deficient zeolite containing 1 to 20 weight percent of binary metal oxides.
zinc-based sorbents for hot gas desulfurization including zinc oxide, natural zeolite, Fe2O3, and CaO. They found the concentration of H2S in the effluent gas is almost zero, although, these sulfidation and regeneration could be performed only at 480°C and 580°C [5]. M. Pineda et al. stated that zinc ferrites exhibit a high reactivity in the sulfidation process but still at temperature range
and M 2 is either a third REO or a group VIIB-VIIIB transition metal oxide), for two applications: hot gas desulfurization/ tar cracking/ secondary reforming, or nanoparticle- promoted combustion.
oxide was higher than that for the supported oxide, but the unsupported mixed metal oxide showed evidence of sintering at higher temperatures, which resulted in a decreased desulfurization capacity. The sulfidation capacity of the zeolite supported
Currently, the Morgantown Energy Technology Center, is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressure`s, and under varying degrees of reducing atmospheres. Thus, high
To improve the desulfurization efficiency of sorbents at low cost, modified semi-coke was used as the substrate for mixed metal oxides (ZFM; oxides of zinc [Zn], iron [Fe], and manganese [Mn]) in hot gas desulfurization.
Test and Characterization of Some Zeolite Supported Gas
A Preliminary Study on the Formation and Removal of COS
After a brief account of the world energy resources and an overview of clean coal technologies, a review of regenerable metal oxide sorbents for cleaning the hot gas is provided. Zinc oxide, copper oxide, calcium oxide, manganese oxide based as well as supported and mixed metal oxide sorbents are treated. Performance analysis of these sorbents, effects of various parameters on the
Development of Supported Sorbents for Hydrogen Sulfide Removal from Fuel Gas A. T. Atimtay Environmental Engineering Department, Middle East Technical University, 06531 Ankara, TIlRKEY Abstract. A general overview of the supported sorbents for the removal of H 2S from coal gas at high temperatures is given. As support material y-Alumina, zirconia, zeolites, etc. can be used. A single …
Gasper-Galvin L, Atimtay A T, Gupta R P. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Industrial & Engineering Chemistry Research, 1998, …
Nine of the sorbents namely; Cu 2 O, Na 2 CO 3, NaHCO 3, K 2 CO 3, CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu 2 O and ZnO had the best performance in terms of the optimum operating temperature.
@article{osti_6935914, title = {TGA studies on supported sorbents at elevated pressures: Capture mechanisms}, author = {Gasper-Galvin, L.D. and Gupta, R.P.}, abstractNote = {The objective of the supported sorbents research at the Morgantown Energy Technology Center (METC) is to develop a hot gas desulfurization sorbent which will have superior attrition resistance, higher temperature
The sorbents consisted of various combinations of copper, molybdenum, and/or manganese oxides supported on a high silica-containing zeolite. These sorbents were tested in a fixed-bed reactor with simulated coal gas at 205 kPa (15 psig). The combination of all three metal oxides displayed synergism in enhancing efficiency for H
15/10/1991 · The amount of mixed metal oxide loaded on the support is sufficient to provide high performance absorption of H 2 S from moderately hot gas. The mixed metal oxide is usually present in the support in an amount from 1 to 20 percent by weight usually from 5 to 15 percent by weight.
Influence of Added Graphite on ZnO Sorbents for Gas Desulfurization MADELENE DANCILA1*, GEORGETA VOICU1, on zinc titanate sorbents for desulfurisation at hot temperatures adding graphite. The sorbents containing ZnO-TiO 2 +ghaphite were obtained through mecanical half-wet mixing of zinc oxide, titane dioxide and graphite method, drying the intermediate product and finally …
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center Morgantown, WV 26505 Keywords : Desulfurization, supported Sorbents, Hot Gas Cleanup INTRODUCTION Integrated gasification combined cycle (IGCC) system is
A general overview of the supported sorbents for the removal of H 2 S from coal gas at high temperatures is given. As support material γ-Alumina, zirconia, zeolites, etc. can be used. A single or a mixture of metal oxides can be dispersed on the surface and in the pores of the support material
Rapid Functionalization of Mesoporous Materials Directly
Cerium Oxide-Based Sorbents for Regenerative Hot Reformate
Cerium Oxide-Based Sorbents for Regenerative Hot Reformate Gas Desulfurization Zheng Wang and Maria Flytzani-Stephanopoulos* Department of Chemical and Biological Engineering, Tufts University,
Request PDF on ResearchGate Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization This paper describes the results of the development of supported mixed-metal oxide sorbents for
they have been combined with other metal oxides, forming metal oxide sorbents. Sulfidation experiments were carried out at 627 o Cusing a gas mixture composed of 1 …
Influence of Dust on High Temperature Desulfurization of Iron Oxide Sorbent ZHAO Jiantao*, HUANG Jiejie, WU Jinhu, ZHANG Jianming, WANG Yang (Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, Shanxi 030001, China)
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center
FIELD GROU SUB-ROUP Desulfurization, Phosphoric Acid,Fuel Cells, Diesel Fuel, I Mixed Oxide Sorbents, fuel using regenerable copper-based mixed metal oxide sorbents was developed for incorporation in modular phosphoric acid fuel cell (PAFC) generators. Removal of greater than 60% of the sulfur in diesel fuel was demonstrated, and sorbent sulfur loadings of approximately 1 wt% were
A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical
Simultaneous Hot Desulfurization and Improved Filtration
“Hot Coal Gas” Desulfurization by Perovskite-type Sorbents Vijayanand Rajagopalan and Michael D. Amiridis* Department of Chemical Engineering, The University of South…
Gasper-Galvin, L.D. and Atimtay, A. T., “Zeolite Supported Copper Sorbents for Hot Gas Desulfurization,” Paper presented in the Summer AIChE Meeting, Pittsburgh, PA, August 1991. Atimtay, A. T ., “Use of Zeolites as Support Material for Regenerable Sorbents” Paper presented at the NATO/ ASI on Multifunctional Mesoporous Inorganic Solids, April 5-17, 1992, Sintra, Portugal.
of high-temperature desulfurization systems using mixed metal oxide sorbents over the last decade [McDaniel et al., 1995], and a need exists for the development of more efficient sorbents for the lower end of the high temperature range of operation, i.e., the so-called “low” temperature
Several Zn-based adsorbents, pure metal oxide (ZnO) and mixed oxides (zinc ferrite and zinc titanate) have been attractive for gas-phase high-temperature desulfurization because of their favorable sulfidation thermodynamics, high H 2 S removal efficiency, good sulfur-loading capacity, high regenerability, and sufficient strength [37,38].
Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation.
Molecules Free Full-Text Adsorptive Desulfurization of
98/02032 Reduction of spalling in mixed metal oxide
Influence of Added Graphite on ZnO Sorbents for Gas
Performance Model of the Fluidized Bed Copper Oxide
Mixed Metal Oxide and Mixed Metal Oxide Coal Fossil Fuels
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas
Bench-scale testing of high-temperature desulfurization
Review of H2S Sorbents at Low-Temperature Desulfurization of Biogas – Free download as PDF File (.pdf), Text File (.txt) or read online for free.
98/02032 Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide : Poston, J. A. U.S. US 5,693,588 (Cl. 502
zinc-based sorbents for hot gas desulfurization including zinc oxide, natural zeolite, Fe2O3, and CaO. They found the concentration of H2S in the effluent gas is almost zero, although, these sulfidation and regeneration could be performed only at 480°C and 580°C [5]. M. Pineda et al. stated that zinc ferrites exhibit a high reactivity in the sulfidation process but still at temperature range
copper-cerium mixed metal oxide sorbents for hot gas desulfurization capable of withstanding the wide temperature range of application and multiple sulfidation-regeneration cycles. The regeneration path was reported as (Li et al. 1997).ion exchanged zeolites as the potential sorbents for desulfurization over a wide temperature range. An effort is made in this work to include the various
Abstract −The desulfurization abilities using GC/microreactor have been examined for CuO-Fe2O3 sorbents with respect to calcination temperatures of 700, 900 and 1,100 o C. CuO was used as a main active component, Fe
1: Gasper-Galvin L D, Atimtay A T, Gupta R P. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Industrial & Engineering Chemistry Research, 1998, 37(10): 4157-4166
The Mn x Mo y /KIT-1 sorbents with different Mn/Mo molar ratio were prepared by a sol–gel method. The structural properties of these sorbents were investigated by XRD, N 2-adsorption, H 2-TPR, TEM, SEM, XPS and TG/DSC techniques.
Investigation of CuO/mesoporous SBA-15 sorbents for hot gas desulfurization Investigation of CuO/mesoporous SBA-15 sorbents for hot gas desulfurization Karvan, Oğuz; Atakül, Hüsnü 2008-09-01 00:00:00 Metal oxides, are widely used as sorbents to remove H 2 S from hot gases produced by gasification processes.
Copper-cobalt, copper-cerium mixed metal oxide and mixed metal oxide supported- ions exchanged on natural zeolite (MMS-IZ) sorbents are studied in this work. Copper-cobalt mixed system is a good candidate for low temperature desulfurization while copper-cerium exhibits the high temperature stability and high performance. The reduced form of cerium oxide (CeOn) in copper-cerium reduced the H2S
A multiple metal oxide sorbent supported on a zeolite of substantially silicon oxide is used for the desulfurization of process gas streams, such as from a coal gasifier, at temperatures in the range of about 1200.degree. to about 1600.degree.
Cerium Oxide-Based Sorbents for Regenerative Hot Reformate Gas Desulfurization Zheng Wang and Maria Flytzani-Stephanopoulos* Department of Chemical and Biological Engineering, Tufts University,
Hot Gas Desulfurization (HGD) technology, which is predicted for use in Clean Coal Technologies (IGCC, PFBC & MCFC), is a technique for removing sulfur compounds (H2S, COS) from fuel gas or coal gas by using regenerable metal oxide sorbents at a high temperature (350-650oC) and high pressure (20-30 bar) [Song et al., 2000]. HGD technology is a key element in the optimal devel-opment of the
Present technologies for hydrogen sulfide removal from
Sorbent for use in hot gas desulfurization (Patent
Cerium Oxide-Based Sorbents for Regenerative Hot Reformate Gas Desulfurization Zheng Wang and Maria Flytzani-Stephanopoulos* Department of Chemical and Biological Engineering, Tufts University,
Abstract. Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures.
Development of Supported Sorbents for Hydrogen Sulfide Removal from Fuel Gas A. T. Atimtay Environmental Engineering Department, Middle East Technical University, 06531 Ankara, TIlRKEY Abstract. A general overview of the supported sorbents for the removal of H 2S from coal gas at high temperatures is given. As support material y-Alumina, zirconia, zeolites, etc. can be used. A single …
Several Zn-based adsorbents, pure metal oxide (ZnO) and mixed oxides (zinc ferrite and zinc titanate) have been attractive for gas-phase high-temperature desulfurization because of their favorable sulfidation thermodynamics, high H 2 S removal efficiency, good sulfur-loading capacity, high regenerability, and sufficient strength [37,38].
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center Morgantown, WV 26505 Keywords : Desulfurization, supported Sorbents, Hot Gas Cleanup INTRODUCTION Integrated gasification combined cycle (IGCC) system is
A core-in-shell sorbent is described herein. The core is reactive to the compounds of interest, and is preferably calcium-based, such as limestone for hot gas desulfurization. The shell is a porous protective layer, preferably inert, which allows the reactive core to remove the desired compounds while maintaining the desired physical
The sorbents consisted of various combinations of copper, molybdenum, and/or manganese oxides supported on a high silica-containing zeolite. These sorbents were tested in a fixed-bed reactor with simulated coal gas at 205 kPa (15 psig). The combination of all three metal oxides displayed synergism in enhancing efficiency for H
The experimental section describes the preparation and characterization methods used in this work for synthesizing sorbents. which gives an overview about the need of new technologies for coal utilization and importance of hot gas clean up. and composition of the mixed metal oxide sorbent and mixed metal oxide supported-ion exchanged zeolite (MMS-IZ) sorbents This thesis is comprised of
Gasper-Galvin, L.D. and Atimtay, A. T., “Zeolite Supported Copper Sorbents for Hot Gas Desulfurization,” Paper presented in the Summer AIChE Meeting, Pittsburgh, PA, August 1991. Atimtay, A. T ., “Use of Zeolites as Support Material for Regenerable Sorbents” Paper presented at the NATO/ ASI on Multifunctional Mesoporous Inorganic Solids, April 5-17, 1992, Sintra, Portugal.
Yang, H., 2007, “Gas Phase Desulfurization Using Regenerable Microfibrous Entrapped Metal Oxide Based Sorbent for Logistic PEM Fuel Cell Applications,” Ph.D. …
Zeolite-supported metal oxide sorbents for hot-gas desulfurization Galvin, L.D.G.; Atımtay, A.T.; Gupta, R.P. Impact of aqueous impregnation on the long-range ordering and mesoporous structure of cobalt containing MCM-41 and SBA-15 materials
@article{osti_6935914, title = {TGA studies on supported sorbents at elevated pressures: Capture mechanisms}, author = {Gasper-Galvin, L.D. and Gupta, R.P.}, abstractNote = {The objective of the supported sorbents research at the Morgantown Energy Technology Center (METC) is to develop a hot gas desulfurization sorbent which will have superior attrition resistance, higher temperature
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin * Federal Energy Technology Center, U.S. Department of Energy, …
Similarly, advances made in sorbent technology, especially metal oxide sorbents, have resulted in effective sulfur emissions mitigation. Current use of metal oxide sorbents, however, has focused on, regenerable formulations which have excellent sulfur affinity but high physical attrition, resulting in poor overall economics.
Desulfurization of and Tar Removal from Gasifier Effluents
Present technologies for hydrogen sulfide removal from
After a brief account of the world energy resources and an overview of clean coal technologies, a review of regenerable metal oxide sorbents for cleaning the hot gas is provided. Zinc oxide, copper oxide, calcium oxide, manganese oxide based as well as supported and mixed metal oxide sorbents are treated. Performance analysis of these sorbents, effects of various parameters on the
zinc-based sorbents for hot gas desulfurization including zinc oxide, natural zeolite, Fe2O3, and CaO. They found the concentration of H2S in the effluent gas is almost zero, although, these sulfidation and regeneration could be performed only at 480°C and 580°C [5]. M. Pineda et al. stated that zinc ferrites exhibit a high reactivity in the sulfidation process but still at temperature range
Abstract. Desulfurization of natural gas is achieved commercially by absorption with liquid amine solutions. Adsorption technology could potentially replace the solvent extraction process, particularly for the emerging shale gas wells with production rates that are generally lower than that from the large conventional reservoirs, if a superior
Keywords: zinc titanate sorbents, Hot-Gas Desulfurization (HGD), graphite The gas desulphurisation at high temperatures (HTGD) is one of the main process for retention of H
Investigation of nano-CuO/mesoporous SiO 2 materials as
Douglas Patrick Harrison Wikipedia
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin * Federal Energy Technology Center, U.S. Department of Energy, …
Gasper-Galvin L, Atimtay A T, Gupta R P. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Industrial & Engineering Chemistry Research, 1998, …
Development of Supported Sorbents for Hydrogen Sulfide Removal from Fuel Gas A. T. Atimtay Environmental Engineering Department, Middle East Technical University, 06531 Ankara, TIlRKEY Abstract. A general overview of the supported sorbents for the removal of H 2S from coal gas at high temperatures is given. As support material y-Alumina, zirconia, zeolites, etc. can be used. A single …
of high-temperature desulfurization systems using mixed metal oxide sorbents over the last decade [McDaniel et al., 1995], and a need exists for the development of more efficient sorbents for the lower end of the high temperature range of operation, i.e., the so-called “low” temperature
Abstract −The desulfurization abilities using GC/microreactor have been examined for CuO-Fe2O3 sorbents with respect to calcination temperatures of 700, 900 and 1,100 o C. CuO was used as a main active component, Fe
The experimental section describes the preparation and characterization methods used in this work for synthesizing sorbents. which gives an overview about the need of new technologies for coal utilization and importance of hot gas clean up. and composition of the mixed metal oxide sorbent and mixed metal oxide supported-ion exchanged zeolite (MMS-IZ) sorbents This thesis is comprised of
A general overview of the supported sorbents for the removal of H2S from coal gas at high temperatures is given. As support material γ-Alumina, zirconia, zeolites, etc. can be used.
Review of H2S Sorbents at Low-Temperature Desulfurization of Biogas – Free download as PDF File (.pdf), Text File (.txt) or read online for free.
Nine of the sorbents namely; Cu 2 O, Na 2 CO 3, NaHCO 3, K 2 CO 3, CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu 2 O and ZnO had the best performance in terms of the optimum operating temperature.
After a brief account of the world energy resources and an overview of clean coal technologies, a review of regenerable metal oxide sorbents for cleaning the hot gas is provided. Zinc oxide, copper oxide, calcium oxide, manganese oxide based as well as supported and mixed metal oxide sorbents are treated. Performance analysis of these sorbents, effects of various parameters on the
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center
Abstract. Extrudates of regenerable mixed-metal oxide sorbents including zinc ferrite, copper-modified zinc ferrite, and zinc titanate were prepared and tested for their potential to remove hydrogen sulfide (H 2 S) from coal gasifier gas in a high-temperature high-pressure (HTHP) fixed-bed reactor.
A general overview of the supported sorbents for the removal of H 2 S from coal gas at high temperatures is given. As support material γ-Alumina, zirconia, zeolites, etc. can be used. A single or a mixture of metal oxides can be dispersed on the surface and in the pores of the support material
The Author(s) 2016 removal for solid oxide fuel Reprints
REMOVAL OF HYDROGEN SULFIDE BY REGENERABLE METAL OXIDE
Hot-gas desulfurization research has focused on regenerable mixed-metal oxide sorbents that can reduce the sulfur in coal-derived fuel-gas to less than 20 ppmv and can be regenerated in a cyclic manner with air for multicycle operation.
Get this from a library! Test and characterization of some zeolite supported gas phase desulfurization sorbents.. [Charles Rong; Deryn Chu; John Hopkins; U.S. Army Research Laboratory.] — This report presents the results of sulfidation and regeneration of mixed metal oxide supported on zeolite-Y for hydrogen sulfide (H2S) at 650 and 800 deg C
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin * Federal Energy Technology Center, U.S. Department of Energy, …
Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures.
Desulfurization of fuel gas can be achieved by using metal oxide sorbents that form stable sulfides. Elseviers and Verelst (1999) analysed the purification performance of different metal oxides between 350 K and 923 K, and ranked Cu, Zn, Co and Mo as being the most useful.
FIELD GROU SUB-ROUP Desulfurization, Phosphoric Acid,Fuel Cells, Diesel Fuel, I Mixed Oxide Sorbents, fuel using regenerable copper-based mixed metal oxide sorbents was developed for incorporation in modular phosphoric acid fuel cell (PAFC) generators. Removal of greater than 60% of the sulfur in diesel fuel was demonstrated, and sorbent sulfur loadings of approximately 1 wt% were
Desulfurization of Hot Coal Gas Springer for Research
Investigation of nano-CuO/mesoporous SiO 2 materials as
and M 2 is either a third REO or a group VIIB-VIIIB transition metal oxide), for two applications: hot gas desulfurization/ tar cracking/ secondary reforming, or nanoparticle- promoted combustion.
Hot Gas Desulfurization (HGD) technology, which is predicted for use in Clean Coal Technologies (IGCC, PFBC & MCFC), is a technique for removing sulfur compounds (H2S, COS) from fuel gas or coal gas by using regenerable metal oxide sorbents at a high temperature (350-650oC) and high pressure (20-30 bar) [Song et al., 2000]. HGD technology is a key element in the optimal devel-opment of the
Review of H2S Sorbents at Low-Temperature Desulfurization of Biogas – Free download as PDF File (.pdf), Text File (.txt) or read online for free.
number of metal oxides from being used as a high temperature desulfurization sorbent. Westmoreland and Harrison(2) in their 1976 paper screened 28 solids with respect to their high temperature desulfurization potentials.
Similarly, advances made in sorbent technology, especially metal oxide sorbents, have resulted in effective sulfur emissions mitigation. Current use of metal oxide sorbents, however, has focused on, regenerable formulations which have excellent sulfur affinity but high physical attrition, resulting in poor overall economics.
@article{osti_6935914, title = {TGA studies on supported sorbents at elevated pressures: Capture mechanisms}, author = {Gasper-Galvin, L.D. and Gupta, R.P.}, abstractNote = {The objective of the supported sorbents research at the Morgantown Energy Technology Center (METC) is to develop a hot gas desulfurization sorbent which will have superior attrition resistance, higher temperature
A fly ash sample was used as sorbent for trace element (As, Se, Cd and Zn) species at high temperatures in flue gases from coal gasification. The influence of temperature (550 and 750 °C) and gas composition (with and without H 2 S and HCl) on retention capacity was evaluated.
Abstract. Efficient, regenerable sorbents for removal of H.sub.2 S from moderately high temperature (usually 200.degree. C.-550.degree.C.) gas streams comprise a porous, high surface area aluminosilicate support, suitably a zeolite, and most preferably a sodium deficient zeolite containing 1 to 20 weight percent of binary metal oxides.
Gasper-Galvin, L.D. and Atimtay, A. T., “Zeolite Supported Copper Sorbents for Hot Gas Desulfurization,” Paper presented in the Summer AIChE Meeting, Pittsburgh, PA, August 1991. Atimtay, A. T ., “Use of Zeolites as Support Material for Regenerable Sorbents” Paper presented at the NATO/ ASI on Multifunctional Mesoporous Inorganic Solids, April 5-17, 1992, Sintra, Portugal.
After a brief account of the world energy resources and an overview of clean coal technologies, a review of regenerable metal oxide sorbents for cleaning the hot gas is provided. Zinc oxide, copper oxide, calcium oxide, manganese oxide based as well as supported and mixed metal oxide sorbents are treated. Performance analysis of these sorbents, effects of various parameters on the
12/10/1993 · The mixed metal oxide sorbent of the invention supported on zeolite (preferably copper and molybdenum on 4A Zeolite) has been found to remove hydrogen sulfide from a hydrogen-steam rich gas mixture at 256°-538° C. and regenerated to full capacity …
Test and characterization of some zeolite supported gas
Molecules Free Full-Text Adsorptive Desulfurization of
After a brief account of the world energy resources and an overview of clean coal technologies, a review of regenerable metal oxide sorbents for cleaning the hot gas is provided. Zinc oxide, copper oxide, calcium oxide, manganese oxide based as well as supported and mixed metal oxide sorbents are treated. Performance analysis of these sorbents, effects of various parameters on the
zinc-based sorbents for hot gas desulfurization including zinc oxide, natural zeolite, Fe2O3, and CaO. They found the concentration of H2S in the effluent gas is almost zero, although, these sulfidation and regeneration could be performed only at 480°C and 580°C [5]. M. Pineda et al. stated that zinc ferrites exhibit a high reactivity in the sulfidation process but still at temperature range
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center
and M 2 is either a third REO or a group VIIB-VIIIB transition metal oxide), for two applications: hot gas desulfurization/ tar cracking/ secondary reforming, or nanoparticle- promoted combustion.
copper-cerium mixed metal oxide sorbents for hot gas desulfurization capable of withstanding the wide temperature range of application and multiple sulfidation-regeneration cycles. The regeneration path was reported as (Li et al. 1997).ion exchanged zeolites as the potential sorbents for desulfurization over a wide temperature range. An effort is made in this work to include the various
Influence of Added Graphite on ZnO Sorbents for Gas Desulfurization MADELENE DANCILA1*, GEORGETA VOICU1, on zinc titanate sorbents for desulfurisation at hot temperatures adding graphite. The sorbents containing ZnO-TiO 2 ghaphite were obtained through mecanical half-wet mixing of zinc oxide, titane dioxide and graphite method, drying the intermediate product and finally …
Rapid Functionalization of Mesoporous Materials Directly
Investigation of CuO/mesoporous SBA-15 sorbents for hot
“Regeneration of Sulfided Sorbents and Direct Production of Elemental Sulfur,” presented at the NATO/ASI Symposium on Desulfurization of Hot Coal Gas With Regenerable Metal Oxide Sorbents, Kuşadası, Turkey, July 1996, proceedings to be published.
This paper discusses the results obtained in an ongoing study geared towards developing advanced mixed-metal oxide sorbents for desulfurization of coal-derived fuel gases in the temperature range of 350 to 550°C. The paper focuses on the study related to the development of durable sorbents suitable for fluidized-bed application and addresses thermodynamic considerations, sulfidation kinetics
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center
oxide and a zeolite adsorbent. H Desulfurization of fuel gas can be achieved by using metal oxide sorbents that form stable sulfides. Elseviers and Verelst (1999) analysed the purification performance of different metal oxides between 350K and 923K, and ranked Cu, Zn, Co and Mo as being the most useful. ZnO has been widely used to remove H 2S at moderate low temperatures because of its
Get this from a library! Test and characterization of some zeolite supported gas phase desulfurization sorbents.. [Charles Rong; Deryn Chu; John Hopkins; U.S. Army Research Laboratory.] — This report presents the results of sulfidation and regeneration of mixed metal oxide supported on zeolite-Y for hydrogen sulfide (H2S) at 650 and 800 deg C
Nine of the sorbents namely; Cu 2 O, Na 2 CO 3, NaHCO 3, K 2 CO 3, CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu 2 O and ZnO had the best performance in terms of the optimum operating temperature.
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center Morgantown, WV 26505 Keywords : Desulfurization, supported Sorbents, Hot Gas Cleanup INTRODUCTION Integrated gasification combined cycle (IGCC) system is
98/02032 Reduction of spalling in mixed metal oxide desulfurization sorbents by addition of a large promoter metal oxide : Poston, J. A. U.S. US 5,693,588 (Cl. 502
Currently, the Morgantown Energy Technology Center, is actively investigating alternative hot fuel gas desulfurization sorbents for application to the Integrated Gasification Combined Cycle (IGCC). A sorbent must be highly active towards sulfur at high temperatures and pressure`s, and under varying degrees of reducing atmospheres. Thus, high
A fly ash sample was used as sorbent for trace element (As, Se, Cd and Zn) species at high temperatures in flue gases from coal gasification. The influence of temperature (550 and 750 °C) and gas composition (with and without H 2 S and HCl) on retention capacity was evaluated.
The sorbents consisted of various combinations of copper, molybdenum, and/or manganese oxides supported on a high silica-containing zeolite. These sorbents were tested in a fixed-bed reactor with simulated coal gas at 205 kPa (15 psig). The combination of all three metal oxides displayed synergism in enhancing efficiency for H
A Mn-based sorbent with high desulfurization efficiency were fabricated using various mesoporous silica as support and doping rare earth oxides, and their physical properties were characterized by means of XRD, BET, H 2-TPR, CO 2-TPD, O 2-TPD and UV–Vis techniques.
Desulfurization of and Tar Removal from Gasifier Effluents
New nanostructured sorbents for desulfurization of natural gas
Abstract. Desulfurization of natural gas is achieved commercially by absorption with liquid amine solutions. Adsorption technology could potentially replace the solvent extraction process, particularly for the emerging shale gas wells with production rates that are generally lower than that from the large conventional reservoirs, if a superior
12/10/1993 · The mixed metal oxide sorbent of the invention supported on zeolite (preferably copper and molybdenum on 4A Zeolite) has been found to remove hydrogen sulfide from a hydrogen-steam rich gas mixture at 256°-538° C. and regenerated to full capacity …
Get this from a library! Test and characterization of some zeolite supported gas phase desulfurization sorbents.. [Charles Rong; Deryn Chu; John Hopkins; U.S. Army Research Laboratory.] — This report presents the results of sulfidation and regeneration of mixed metal oxide supported on zeolite-Y for hydrogen sulfide (H2S) at 650 and 800 deg C
Yang, H., 2007, “Gas Phase Desulfurization Using Regenerable Microfibrous Entrapped Metal Oxide Based Sorbent for Logistic PEM Fuel Cell Applications,” Ph.D. …
Nine of the sorbents namely; Cu 2 O, Na 2 CO 3, NaHCO 3, K 2 CO 3, CaO, ZnO, MnO, FeO, and PbO, were determined to have great potential as desulfurization sorbents. Cu 2 O and ZnO had the best performance in terms of the optimum operating temperature.
Abstract. Extrudates of regenerable mixed-metal oxide sorbents including zinc ferrite, copper-modified zinc ferrite, and zinc titanate were prepared and tested for their potential to remove hydrogen sulfide (H 2 S) from coal gasifier gas in a high-temperature high-pressure (HTHP) fixed-bed reactor.
copper-cerium mixed metal oxide sorbents for hot gas desulfurization capable of withstanding the wide temperature range of application and multiple sulfidation-regeneration cycles. The regeneration path was reported as (Li et al. 1997).ion exchanged zeolites as the potential sorbents for desulfurization over a wide temperature range. An effort is made in this work to include the various
Abstract. Natural gas, refinery gas, and coal gas contain acid gases such as hydrogen sulfide (H 2 S) and carbon dioxide that must be removed from the gas stream due to the toxicity of H 2 S and to prevent corrosion to piping and production facility caused by the acid gases.
1: Gasper-Galvin L D, Atimtay A T, Gupta R P. Zeolite-supported metal oxide sorbents for hot-gas desulfurization. Industrial & Engineering Chemistry Research, 1998, 37(10): 4157-4166
98/02032 Reduction of spalling in mixed metal oxide
Regenerative Cu La zeolite supported desulfurizing sorbents
A number of mixed metal oxide sorbents were tried, to achieve better performance in H 2 S removal, including ZnFe 2 O 4 (Ahmed et al., 2000) and Zn 2 TiO 4 (Lew and Sarofim, 1992a). Lew and Sarofim reported that Zn–Ti–O sorbent exhibited a high activity for hydrogen sulfide removal via a mechanism of desulfurization similar with that on ZnO. However, there are still some disadvantages for
A NOVEL SUPPORTED SORBENT FOR HOT GAS DESULFURIZATION Aysel T. Atimtay Lee D. Gasper-Galvin James A. Poston Morgantown Energy Technology Center Morgantown, WV 26505 Keywords : Desulfurization, supported Sorbents, Hot Gas Cleanup INTRODUCTION Integrated gasification combined cycle (IGCC) system is
Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization Lee D. Gasper-Galvin* Federal Energy Technology Center, U.S. Department of Energy, 3610 Collins Ferry Road,…
The experimental section describes the preparation and characterization methods used in this work for synthesizing sorbents. which gives an overview about the need of new technologies for coal utilization and importance of hot gas clean up. and composition of the mixed metal oxide sorbent and mixed metal oxide supported-ion exchanged zeolite (MMS-IZ) sorbents This thesis is comprised of
@article{osti_6935914, title = {TGA studies on supported sorbents at elevated pressures: Capture mechanisms}, author = {Gasper-Galvin, L.D. and Gupta, R.P.}, abstractNote = {The objective of the supported sorbents research at the Morgantown Energy Technology Center (METC) is to develop a hot gas desulfurization sorbent which will have superior attrition resistance, higher temperature
High-Temperature H2S Removal from Fuel Gases by Regenerable Zinc Oxide-Titanium Dioxide Sorbents Early work on hot gas desulfurization employed single oxide sorbents, especially iron oxide and zinc oxide *To whom all correspondence should be addressed. Present address: Department of Chemical Engineering, Louisiana State University, Baton Rouge, LA 70803. (MERC, 1978; …
Request PDF on ResearchGate Zeolite-Supported Metal Oxide Sorbents for Hot-Gas Desulfurization This paper describes the results of the development of supported mixed-metal oxide sorbents for
Hot Gas Desulfurization (HGD) technology, which is predicted for use in Clean Coal Technologies (IGCC, PFBC & MCFC), is a technique for removing sulfur compounds (H2S, COS) from fuel gas or coal gas by using regenerable metal oxide sorbents at a high temperature (350-650oC) and high pressure (20-30 bar) [Song et al., 2000]. HGD technology is a key element in the optimal devel-opment of the